High Temperature Oxidationan overview ScienceDirect
During high temperature HT oxidation usually chromium or alumina scales develop on the surface of alloys However in the case of local depletion of one of these elements oxygen can penetrate into the alloy and result in internal or grain boundary oxidation
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The mean oxidation rate at 1273 K is 132–271 times higher than that at 873 K Based on the oxidation rates of different graphite grades at three different regimes GLM is suggested for the application in high temperature environments and as a high temperature electrode for fuel cells and batteries 4 Conclusions
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At high temperatures most metals will inevitably oxidise over a wide range of conditions The practical issues of material lifetimes and corrosion protection methods therefore centre around the rate of oxidation and how to control reaction morphology
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Cyclic oxidation tests were performed for these alloys at 1150°C Cyclic oxidation tests are one of the basic criteria for assessing the properties of protective coatings and superalloys Cyclic heating to a high temperature and cooling to room temperature causes the growth of ox
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OXIDATION RESISTANT HIGH TEMPERATURE MATERIALS Navy missiles are becoming faster and are also able to intercept incoming targets at greater ranges Unfortunately increased missile speed means increased material temperatures and some missile components are exposed to temperatures exceeding 5000°F
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A chemical mechanism for low to high temperature oxidation of methylcyclohexane as a component of transportation fuel surrogates Combustion and Flame 2015 162 4
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by lowering the temperature of the flame by using a higher gas velocity and density and employing effective substrate cooling Keywords WC Co17 coating NiCr80/20 coating oxidation HVOF spraying thermal spraying oxidation kinetics high temperature oxidation coating oxidation decarburization of WC Co17
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High entropy metal carbides have recently been arousing considerable interest Nevertheless their high temperature oxidation behavior is rarely studied Herein the high temperature oxidation behavior of Hf 0 2 Zr 0 2 Ta 0 2 Nb 0 2 Ti 0 2 C high entropy metal carbide HEC 1 was investigated at K in air for 120 minutes The results
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oxidation of spray powder is a complex phenomenon involving selective and volatile oxidation and formation of solid oxide Oxidation of the coating is strongly related to the temperature of the particles and combustion gas Oxidation of the spray powder can take place in solid or molten state
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However high temperature oxidation induces decarbonization and enhances porosity of the composites After oxidation at 400 °C for 300 h porosity of the composite changes just a little indicating that graphite can exist stably at 400 °C for a long time
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New high temperature materials are required to increase energy conversion efficiency of thermal cycles such as gas turbine engines To use Functionally graded materials FGMs at high temperatures oxidation/corrosion resistance is very important The oxidation
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In the frame of two DFG funded projects we are studying mechanisms of high temperature oxidation of superalloys for over 10 years These research projects are a continuation of a long tradition of earlier work at the Chair of Surface Science and Corrosion While the earlier research was mainly concerned with high temperature corrosion under
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1995 Stress effects in high temperature oxidation of metals International Materials Reviews Vol 40 No 1 pp 1 40
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High Temperature Oxidation and Corrosion of Metals Second Edition provides a high level understanding of the fundamental mechanisms of high temperature alloy oxidation uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature gas chemistry and alloy composition
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As well known graphite is sensitive to oxidation at high temperature Oxidation highly dependent on temperature and exposition time At significantly high T >1500°C oxidation limited to surface for exposition times of 10s Greater mass loss observed for longer exposition times but still attack limited to surface
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High temperature oxidation HTO of metals and alloys is a scale forming oxidation process in gaseous environments
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The high temperature oxidation of copper is adequately covered in the book of Kofstad 53 A review by Belousov54 is devoted to the catastrophic oxidation of copper The present review differs by that a single approach is used to consider both high temperature oxidation of copper to which the classic model of Wagner is applicable and
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The high‐temperature oxidation of metals always attracts attention from the readers and researchers community as the enthusiastic subject of investigation This area covers both theoretical predication and satisfactory subject of investigation based on the various combined areas such as metallurgical chemical and physical discipline with thermodynamic predication 7
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High temperature oxidation materials such as the austenitic stainless steel 316L is known to exhibit good corrosion and oxidation resisting qualities Cerium oxide coatings on stainless steels reverses the diffusion mechanism from iron outward diffusion to
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DefinitionWhat does High Temperature Oxidation mean High temperature oxidation refers to a chemical reaction involving a metallic object and atmospheric oxygen that produces corrosion at elevated temperatures Such corrosion can be prevented
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Liu Y et al Effect of Al content on high temperature oxidation resistance of AlxCoCrCuFeNi high entropy alloys x = 0 0 5 1 1 5 2 Vaccum 169 108837 2019 CAS Article Google Scholar
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High Temperature Steam Oxidation of Zirconium Alloys Fuel cladding is the outer layer of the fuel rods standing between the reactor coolant and the nuclear fuel i e fuel pellets It is made of a corrosion resistant material with low absorption cross section for thermal neutrons 0 18 10 –24 cm 2 usually zirconium alloy
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This work describes an oxidation process of iron–iron oxide core–shell nanowires at temperatures between 100 °C and 800 °C The studied nanomaterial was synthesized through a simple chemical reduction of iron trichloride in an external magnetic field under a constant flow of
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For the pure Ni foil high temperature oxidation resulted in dominant peaks at 853 7 855 7 and 861 0 eV corresponding to the main peaks of Ni oxides Supplementary Fig S7 and Supplementary
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This chapter explains the brief understanding of the high‐temperature oxidation of pure metals such as iron copper and zinc Effect of crystal structure from fcc to bcc and hcp on the role of high‐temperature oxidation is described briefly
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Introduction to the High Temperature Oxidation of Metals 2nd Edition Neil Birks Gerald H Meier and Fred S Pettit Frontmatter More information Introduction the formation of a solid reaction product usually an oxide which separates the component and atmosphere The rate of further reaction is controlled by transport
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The mechanism of high temperature oxidation of copper was the subject of numerous experimental and theoretical studies of the first and beginning of the second half of the last century 5868 It was established that in the temperature range of 350–1050 °C copper is oxidized according to a parabolic time law The temperature dependences of the parabolic rate constants k obtained by
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As such the ability of high temperature alloys to form an adherent slow growing and protective surface oxide scale nominally consisting of chromia Cr 2 O 3 and alumina Al 2 O 3 is
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Oxidation is the reaction between the metal and oxygen either as O 2 or H 2 O Oxidation can be either beneficial or detrimental depending on the properties of the oxide layer that forms in the reaction Oxides of chromium silicon and aluminium are protective 253
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The laser metal deposition LMD additive manufacturing process was applied to produce TiC/Inconel 625 composite parts The high temperature oxidation performance of the LMD processed parts and the underlying physical/chemical mechanisms were systematically studied The incorporation of the TiC reinforcement in the Inconel 625 improved the oxidation resistance of the LMD processed
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The high temperature oxidation behavior of a new family of refractory high entropy alloys HEAs with compositions of W Mo Cr Ti Al Nb Mo Cr Ti Al and Ta Mo Cr Ti Al was studied at 1000°C and 1100°C Based on these equimolar starting compositions the main incentive of
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This chapter explains the brief understanding of the high‐temperature oxidation of pure metals such as iron copper and zinc Effect of crystal structure from fcc to bcc and hcp on the role of high‐temperature oxidation is described briefly Simultaneously the effect of grain size of these metals and grain boundary displacement during oxidation process are described very clearly
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Hall Jon A High temperature oxidation of sterling silver 1981 Thesis Rochester Institute of Technology Accessed from This Thesis is brought to you for free and open access by RIT Scholar Works It has been accepted for inclusion in Theses by an authorized administrator of RIT Scholar Works For more information please contact
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High Temperature Physical and Chemical Stability and Oxidation Reaction Kinetics of Ni−Cr Nanoparticles Md Taibur Rahman † Kathryn Mireles † Juan J Gomez Chavez ‡ Pui Ching Wo † JoséMarcial † M R Kessler † John McCloy † C V Ramana ‡ and Rahul Panat † †School of Mechanical and Materials Engineering Washington State University Pullman Washington 99163
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